Transactions of Nanjing University of Aeronautics & Astronautics
Preparation of LargeScale DoubleSide BDD Electrodes and Their Electrochemical Performances
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Abstract:
Boron doped diamond (BDD) performs well in electrochemical oxidatio n for organic pollutants thanks to its wide electrochemical window and superior chemical stability. We presented a method to obtain welladherent largescale BDD/Nb electrode by the modified hot filament chemical vapor deposition system (HFCVD). SiC particles were sand blasted to enhance the adhesion of BDD coating. The BDD coating was then deposited on both sides of Nb which was placed vertically and closely with filament grids on both sides. The BDD/Nb electrodes had no deformation because the thermal deformations of the BDD films on both sides of the Nb substrate conteracted each other during cooling process after deposition. The surface morphology and purity of the BDD/Nb electrode were analyzed by Raman and scanning elestron microscope (SEM) techniques. Scratch test was used to investigate the adhesion of BDD films. The electrochemical performances were measured by cyclic voltammetry test. The BDD electrode at the B/C ratio of 2 000×１０－６ held a higher oxygen evolution potential thanks to its high sp3 carbon content.Accelerated life test illustrated that the sandblasting pretreatment obviously enhanced th e adhesion of BDD coating which resulted in a longer service duration than the un-sandblasted one.
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